Free Particle
In the time-independent Schrodinger's equation, when there is no potential
−ℏ22m∂2∂2xϕE=EϕE
Let
k=√2mEℏ
The general solution is
ϕE(x,0)=Aeikx+Be−ikx
which is not normalizable. So, a free particle with single plane wave as wave function is not physical. The wave function can only be a wave packet.
Ψ(x,0)=Ne−(x−x0)22a2eikx
which is a superposition of momentum eigenfunctions
Ψ(x,0)=∫dkeikx√2πf(k)
where
f(k)=e−a2(k−k0)22˜Ne−ikx0
So, the wave function should be
Ψ(x,t)=∫dkf(k)1√2πei(kx−ωt)
Potential Step
When the energy of the particle
E is smaller than
V0
The general solution is
ϕE(x)={Aeikx+B−ikx, x<0 Ce−αx+Deαx, x>0
where
k=√2mEℏ
and
α=√2m(V0−E)ℏ
Let it be scattering from left to right, so
D=0
ϕE(x)={Aeikx+B−ikx, x<0 Ceαx, x>0
ϕE and
ϕ′E are continuous at
x=0, so
{A+B=CikA−ikB=−αC
So,
B=ik+αik−αA=k−iαk+iαA
and
C=2ikik−αA=2kk+iαA
Define
t≡BA=k−iαk+iαA
and
r≡CA=2kk+iαA
to illustrate the ratio of the amplitude of the transmitted and reflected wave to the incident wave.
The transmission probability is
T=|JC||JA|=|C|2αm|A|2km=|t|2αk=4αk(k+α)2
and the reflection probability is
R=|JB||JA|=|B|2km|A|2km=|r|2=(k−αk+α)
Similarly for
E>V0.
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